SYNTHESIS AND CHARACTERIZATION OF SULFOXIDE ADDUCTS OF URANYL BIS(BETA-DIKETONATES) - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [UO2(DBM)(2)CENTER-DOT-C6H5CH2SOCH3]

Authors
KANNAN S VENUGOPAL V PILLAI MRA DROEGE PA BARNES CL
Citation
S. Kannan et al., SYNTHESIS AND CHARACTERIZATION OF SULFOXIDE ADDUCTS OF URANYL BIS(BETA-DIKETONATES) - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [UO2(DBM)(2)CENTER-DOT-C6H5CH2SOCH3], Polyhedron, 15(1), 1996, pp. 97-101
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
1
Year of publication
1996
Pages
97 - 101
Database
ISI
SICI code
0277-5387(1996)15:1<97:SACOSA>2.0.ZU;2-P
Abstract
The uranyl complexes of the type [UO2(OO)(2) . S] (where OO = thenoylt rifluoroacetonate ion, [C4H3SCOCHCOCF3](-); dibenzoylmethanate ion, [C 6H5COCH COC6H5](-); S=PhCH(2)SOCH(3), PhSOPh or PhCH(2)SOCH(2)Ph) were prepared and characterized by elemental analyses, IR, H-1, C-13{H-1} and F-19{H-1} NMR spectroscopic techniques. The structure of the compl ex [UO2(DBM)(2) . PhCH(2)SOCH(3)] was solved by a single-crystal X-ray diffraction method. The structure determination shows that the uraniu m atom has a pentagonal bipyramidal geometry.