CRYSTAL-STRUCTURE AND SPECTRA OF TRANS-BIS(PROPANONE, 1-[2-HYDROXYPHENYL]OXIMATO)PALLADIUM(II)

Authors
VOUTSAS GP KERAMIDAS KG LALIAKANTOURI M
Citation
Gp. Voutsas et al., CRYSTAL-STRUCTURE AND SPECTRA OF TRANS-BIS(PROPANONE, 1-[2-HYDROXYPHENYL]OXIMATO)PALLADIUM(II), Polyhedron, 15(1), 1996, pp. 147-151
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
1
Year of publication
1996
Pages
147 - 151
Database
ISI
SICI code
0277-5387(1996)15:1<147:CASOT1>2.0.ZU;2-K
Abstract
The compound [Pd(ppox)(2)], (where ppox(-) denotes the anion of 2-hydr oxy-propiophenoneoxime, C9H10NO2-), was prepared and investigated by m eans of structural and spectroscopic (IR and electronic) measurements. The electronic excitation spectra are consistent with a square-planar PdN2O2 chromophore. The structure was determined by single-crystal X- ray diffraction and consists of discrete Pd(ppox)(2) monomeric units. The Pd atom is in the equatorial plane bonded to two nitrogen atoms an d two oxygen at distances of 1.979(3) and 1.970(2) Angstrom, respectiv ely.