Jh. Holloway et al., TRIS(PENTAFLUOROPHENYL)PHOSPHINE COMPLEXES OF IRIDIUM - MOLECULAR-STRUCTURE OF TRANS-IRBR(CO)(P(C6F5)(3))(2), Polyhedron, 15(1), 1996, pp. 173-175
The first tris(pentafluorophenyl)phosphine complexes of iridium, IrX (
CO){P(C6F5)(3)}(2) (X = Cl, Br), formed by the reaction between IrX(3)
and P(C6F5)(3) in 2-methoxyethanol, are described and the crystal str
ucture of trans-IrBr(CO) {P(C6F5)(3)}(2) is reported.