DESIGN OF NEW HOST COMPOUNDS, CIS-1,4-DIPHENYLCYCLOHEXANE-1,4-DIOL, EXO, EXO-2,5-DIPHENYLNORBORNANE-2,5-DIOL, EXO-EXO-2,6-DIPHENYLBICYCLO[3.3.1]NONANE-2,6-DIOL AND THEIR DERIVATIVES

Authors
TODA F TANAKA K IMAI T BOURNE SA
Citation
F. Toda et al., DESIGN OF NEW HOST COMPOUNDS, CIS-1,4-DIPHENYLCYCLOHEXANE-1,4-DIOL, EXO, EXO-2,5-DIPHENYLNORBORNANE-2,5-DIOL, EXO-EXO-2,6-DIPHENYLBICYCLO[3.3.1]NONANE-2,6-DIOL AND THEIR DERIVATIVES, Supramolecular chemistry, 5(4), 1995, pp. 289-295
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Supramolecular chemistry → ACNP
ISSN journal
10610278
Volume
5
Issue
4
Year of publication
1995
Pages
289 - 295
Database
ISI
SICI code
1061-0278(1995)5:4<289:DONHCC>2.0.ZU;2-9
Abstract
The title host compounds were designed. Of these, cis-1,4-diphenylcycl ohexane-1,4-diol (4) showed very high inclusion ability for alcohols a nd phenols, although its trans-isomer (3) showed none. By applying the selective inclusion complexation behaviour of 4, separation of isomer s was accomplished. Rac-exo,exo-2,5-diphenylnorbornane-2,5-diol (9a) a nd -exo,exo-2,6-diphenylbicyclo[3.3.1]nonane-2,6-diol (11a) showed ver y poor inclusion ability. The optically active derivative of 11a (11b) showed none. In order to determine the reasons for the inclusion tend encies of the newly designed host compounds, molecular arid crystal st ructures were studied by X-ray analysis.