THE EFFECT OF HYDROSTATIC-PRESSURE ON THE POSITION OF THE 1616CM(-1) RAMAN LINE OF POLY(ETHYLENE-TEREPHTHALATE)

Authors
WEBSTER S BOWER DI
Citation
S. Webster et Di. Bower, THE EFFECT OF HYDROSTATIC-PRESSURE ON THE POSITION OF THE 1616CM(-1) RAMAN LINE OF POLY(ETHYLENE-TEREPHTHALATE), Polymer, 36(22), 1995, pp. 4351-4353
Citations number
21
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
36
Issue
22
Year of publication
1995
Pages
4351 - 4353
Database
ISI
SICI code
0032-3861(1995)36:22<4351:TEOHOT>2.0.ZU;2-P
Abstract
The effect of hydrostatic pressures up to 500 MPa on the position of t he 1616cm(-1) Raman line of amorphous, randomly oriented poly(ethylene terephthalate) has been studied. The shift varies linearly with press ure, with a sensitivity of 5.6+/-0.3cm(-1) GPa(-1). This value is in e xcellent agreement with the value of 6.4+/-1.4 cm(-1) GPa(-1) recently deduced from measurements of the sensitivity of the position to tensi le stress for four combinations of polarization directions of incident and scattered light.