V. Constantoudis et N. Theodorakopoulos, QUANTUM SIGNATURES OF CHAOS IN INTEGRABLE SYSTEMS, Journal of physics. A, mathematical and general, 28(20), 1995, pp. 5701-5708
Two fundamental quantum signatures of classically chaotic behaviour, l
arge second derivatives and the logarithmic time barrier separating cl
assical from quantum dynamics, have been observed near the separatrix
of an integrable spin system. A systematic study in the neighbourhood
of the separatrix reveals that the error in semiclassical eigenvalues
(measured in units of the quantum level spacing) approaches a finite v
alue at the classical limit. The generic factor which limits the valid
ity of the correspondence principle is the presence of classical insta
bilities; chaotic behaviour is one such case; the separatrix of an int
egrable system is another.