FREE-JET ABSORPTION MILLIMETER-WAVE SPECTRUM OF THIOANISOLE

Authors
VELINO B MELANDRI S CAMINATI W FAVERO PG
Citation
B. Velino et al., FREE-JET ABSORPTION MILLIMETER-WAVE SPECTRUM OF THIOANISOLE, Gazzetta chimica italiana, 125(8), 1995, pp. 373-376
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
125
Issue
8
Year of publication
1995
Pages
373 - 376
Database
ISI
SICI code
0016-5603(1995)125:8<373:FAMSOT>2.0.ZU;2-6
Abstract
The microwave spectrum of thioanisole has been assigned using a free-j et millimeter wave spectrometer in the frequency range 60-78 GHz. The carbon atom of the methyl group was found to lie in the plane of the b enzene ring. The potential energy functions hindering the CH(3)X (X=O, S) rotation are proposed for thioanisole and anisole.