Dg. Lancaster et Jm. Dawes, A PULSED-LASER SOURCE USING STIMULATED RAMAN-SCATTERING AND DIFFERENCE-FREQUENCY MIXING - REMOTE-SENSING OF METHANE IN AIR, Optics communications, 120(5-6), 1995, pp. 307-310
Mid-infrared radiation at 3.43 mu m is generated by difference frequen
cy mixing a 1.064 mu m Nd:YAG laser with a methane gas Raman shifted N
d:YAG (1.064 mu m) laser at 1.54 mu m in KTiOAsO4 (KTA). Using this pu
lsed (7 ns), moderate energy (1 mJ) source we demonstrate the optical
detection of methane in air and measure an absorption coefficient of 1
.2 cm(-1)atm(-1). Additional source characteristics include an intrins
ic wavelength stability defined by the methane Raman vibrational frequ
ency and a moderate linewidth (similar to 1.5 cm(-1)).