DIRECT AZIDATION OF ADAMANTANE AND NORBORNANE BY STABLE AZIDOIODINANES

Authors
KRASUTSKY AP KUEHL CJ ZHDANKIN VV
Citation
Ap. Krasutsky et al., DIRECT AZIDATION OF ADAMANTANE AND NORBORNANE BY STABLE AZIDOIODINANES, Synlett, (10), 1995, pp. 1081
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1995
Database
ISI
SICI code
0936-5214(1995):10<1081:DAOAAN>2.0.ZU;2-U
Abstract
Stable azidoiodinanes 1 and 2 react with norbornane, adamantane and 1, 3-dimethyladamantane upon heating in the presence of catalytic amounts benzoyl peroxide with the formation of the respective azides 6-8 in m oderate yields. In these reactions, reagent 2 can be generated in situ from 2-iodosobenzoic acid and azidotrimethylsilane, and used without isolation.