Water-ethanol mixtures spontaneously produce strong convective effects
, driving the liquid upward in thin films and downward in regular rows
of drops known as ''tears of wine''. We present here a study of this
stationary state, with a specific investigation of the interfacial ins
tability which develops at the crossover between the reservoir and the
thin film. We interpret it as a Rayleigh-like instability, the wavele
ngth of which is mainly controlled by the extension of this crossover
zone.