CARBONYLATION OF DIAMINO-LIGATED METHYLPALLADIUM(II) METHOXIDE COMPLEXES

Authors
KAPTEIJN GM VERHOEF MJ VANDENBROEK MAFH GROVE DM VANKOTEN G
Citation
Gm. Kapteijn et al., CARBONYLATION OF DIAMINO-LIGATED METHYLPALLADIUM(II) METHOXIDE COMPLEXES, Journal of organometallic chemistry, 503(1), 1995, pp. 26-28
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
503
Issue
1
Year of publication
1995
Pages
26 - 28
Database
ISI
SICI code
0022-328X(1995)503:1<26:CODMMC>2.0.ZU;2-6
Abstract
The methylpalladium(II) methoxide complexes [Pd(Me)(OMe)(N similar to N)] (N similar to N = tmeda or bpy) have been synthesized by alkoxide- methanol exchange of [Pd(Me)(OCH(CF3)(2))(N similar to N)] in MeOH. Th e bpy complex undergoes insertion of CO to give either a methyl(methox ycarbonyl) complex [Pd(Me)(CO(2)Me)(bpy)](at -60 degrees C) or an acyl (methoxycarbonyl) complex [Pd(COMe)(CO(2)Me)(bpy)] (at -25 degrees C). Both carbonylated species were isolated and characterized at low temp erature.