Pc. Hauser et al., PROCESS MONITOR FOR AN AMMONIACAL NICKEL SOLUTION EMPLOYING AN INFRARED LIGHT-EMITTING DIODE AND A LOG-RATIO AMPLIFIER, Analyst, 120(10), 1995, pp. 2635-2638
An infrared light-emitting diode with peak-emission intensity at 950 n
m is used to monitor, on-line, the concentration of a nickel hexamine
carbonate solution; This provides a continuous read-out of the concent
ration in an extraction stream and is used to control the process at a
nickel refinery. Previously the data Was obtained by frequent manual
sampling and determination of the concentration by AAS, The transducer
employs fibre-optic cables and a beam splitter in Order to allow comp
lete sealing of the opto-electronics and correction for intensity fluc
tuations of the light source with a log-ratio amplifier, These measure
s allow the device to function with good performance in a hostile envi
ronment of ammonia vapours and large temperature fluctuations.