THE ORIGIN OF THE BAND AT 1462 CM(-1) GENERALLY APPEARING UPON DESORPTION OF PYRIDINE FROM ACIDIC SOLIDS - STEPS TOWARDS A MORE COMPREHENSIVE UNDERSTANDING

Citation
C. Flego et al., THE ORIGIN OF THE BAND AT 1462 CM(-1) GENERALLY APPEARING UPON DESORPTION OF PYRIDINE FROM ACIDIC SOLIDS - STEPS TOWARDS A MORE COMPREHENSIVE UNDERSTANDING, Catalysis letters, 35(1-2), 1995, pp. 125-133
Citations number
24
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
1011372X
Volume
35
Issue
1-2
Year of publication
1995
Pages
125 - 133
Database
ISI
SICI code
1011-372X(1995)35:1-2<125:TOOTBA>2.0.ZU;2-7
Abstract
The pyridine adsorption-desorption method, followed by IR spectroscopy , is generally applied for acidity determination of solid catalysts. A peculiar band at 1462 cm(-1) was observed by several authors upon pyr idine desorption at higher temperatures and was interpreted in various ways. A new complex between Lewis framework acid sites and pyridine i s proposed and several evidences are reported.