Mh. Alexander et Mb. Yang, THEORETICAL INVESTIGATION OF WEAKLY-BOUND COMPLEXES OF B WITH H-2, The Journal of chemical physics, 103(18), 1995, pp. 7956-7965
Continuing an earlier study [M. H. Alexander, J. Chem. Phys. 99, 6014
(1993)] of the B(P-2)... H-2 complex, we report here a further investi
gation into the adiabatic-->diabatic transformation for this system, c
haracterized by three potential energy surfaces (PES's) which become a
symptotically degenerate. The diabatic PES's are used to determine the
energies of the lowest bend-stretch levels of complexes of B(P-2) wit
h either o- or pH(2). The predicted dissociation energies (D-0) are 27
.9 and 38.6 cm(-1) for the complexes with pH(2) and oH(2), respectivel
y, and 37.3 and 48.5 cm for the complexes with oD(2) and pD(2), respec
tively. The motion of the oH(2) moiety within the cluster cannot be de
scribed accurately using a single electronic potential energy surface.
In addition, new ab initio calculations are reported for the complex
of H-2 With B in its first electronic excited state (...2s(2)3s). The
PES for this B(S-2)... H-2 complex is repulsive and nonreactive, at le
ast in the region sampled by vertical electronic excitation of the B(P
-2)... H-2 complex. (C) 1995 American Institute of Physics.