A PREDICATIVE MODEL FOR CERTAIN DIRECTED METALATIONS .4. THE DYNAMIC BEHAVIOR OF THE ORGANOLITHIO INTERMEDIATES FORMED BY METALATION OF P-DIMETHOXYBENZENE (P-DMB)

Authors
SLOCUM DW HAYES G KLINE N
Citation
Dw. Slocum et al., A PREDICATIVE MODEL FOR CERTAIN DIRECTED METALATIONS .4. THE DYNAMIC BEHAVIOR OF THE ORGANOLITHIO INTERMEDIATES FORMED BY METALATION OF P-DIMETHOXYBENZENE (P-DMB), Tetrahedron letters, 36(45), 1995, pp. 8175-8178
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
45
Year of publication
1995
Pages
8175 - 8178
Database
ISI
SICI code
0040-4039(1995)36:45<8175:APMFCD>2.0.ZU;2-M
Abstract
Significant disproportionation between, the mono- and 2,5-bis-metalate d intermediates resulting from metalation of p-DMB has been observed T he best procedure for the generation of each of these intermediates in volves use of an ''incremental'' amount of TMEDA.