L. Lamande et al., DIOXAZAPHOSPHOCANES WITH P-H BOND, NEW CO MPLEXING AGENTS OF CALCIUM COMBINING PHOSPHORYL AND AMIDE GROUPS, Tetrahedron letters, 36(45), 1995, pp. 8201-8204
The formation of calcium complexes with four 2-oxo sigma(4) lambda(5)
dioxazaphosphocanes has been investigated by means of IR and P-31 NMR
spectroscopy. The stoichiometry of these complexes shows that two hete
rocycles moieties containing each an amide and a phosphoryl group are
needed to complex one Ca++ ion.