DIOXAZAPHOSPHOCANES WITH P-H BOND, NEW CO MPLEXING AGENTS OF CALCIUM COMBINING PHOSPHORYL AND AMIDE GROUPS

Citation
L. Lamande et al., DIOXAZAPHOSPHOCANES WITH P-H BOND, NEW CO MPLEXING AGENTS OF CALCIUM COMBINING PHOSPHORYL AND AMIDE GROUPS, Tetrahedron letters, 36(45), 1995, pp. 8201-8204
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
45
Year of publication
1995
Pages
8201 - 8204
Database
ISI
SICI code
0040-4039(1995)36:45<8201:DWPBNC>2.0.ZU;2-N
Abstract
The formation of calcium complexes with four 2-oxo sigma(4) lambda(5) dioxazaphosphocanes has been investigated by means of IR and P-31 NMR spectroscopy. The stoichiometry of these complexes shows that two hete rocycles moieties containing each an amide and a phosphoryl group are needed to complex one Ca++ ion.