Hh. Lu et al., ON THE INDUCTION CRITERION OF THE MARANGONI CONVECTION AT THE GAS LIQUID INTERFACE/, Industrial & engineering chemistry research, 36(2), 1997, pp. 474-482
Some spreading solutes were found to be effective in enhancing the abs
orption rate by provoking interfacial turbulence at the gas-liquid sur
face. In this work, the induction criterion of the Marangoni convectio
n is explored experimentally and theoretically by using aqueous soluti
ons of normal alcohols and surfactants as spreading liquids. The exper
imental results show that aqueous solutions of methanol, ethanol, n-pr
opanol, n-butanol, and n-pentanol may induce significant interfacial t
urbulence, and, on the other hand, aqueous solutions of n-hexanol, n-o
ctanol, SDS, DTMAC, and Triton X-100 do not provoke noticeable interfa
cial turbulence. A dimensionless Marangoni number, Ma, based an film t
hickness delta is satisfactorily developed to evaluate the potentialit
y of a spreading Liquid to produce interfacial turbulence. The critica
l Marangoni number, Ma, c, for the occurrence of the Marangoni convect
ion is also determined.