We present two linear systems with which to evaluate the rotational vo
lume viscosity of dilute polyatomic gas mixtures. These systems are gi
ven in their naturally symmetric constrained singular form. In the tra
nslational-and-rotational-energy approach, the linear system of Monchi
ck, Yun, and Mason can be recovered if one misprint is corrected in th
eir expressions. In the rotational-energy approach, a new linear syste
m is obtained, thereby yielding a new approximation for the volume vis
cosity. We also discuss an extension of the present theory to the vibr
ational volume viscosity. Using iterative methods, we then derive expl
icit expressions for the rotational volume viscosity that can be imple
mented at a low computational cost in practical applications. The accu
racy of these approximate expressions is illustrated with numerical ex
amples. These expressions are relevant to several compressible flow ap
plications, such as flames, chemical reactors, and high-speed entry in
to planetary atmospheres.