Various techniques for measuring self-diffusion coefficients are compa
red and theoretical approaches of selfdiffusion processes briefly disc
ussed. The self-diffusion of components in mixtures of water with orga
nic solvents are used to gain insight into their local structures. An
effect of electrolytes on the solvent structure is shown and an interr
elation between solvation of ions and the structure of binary solvents
is discussed.