E. Beyou et al., NEW FLUORINATED POLYSILOXANES CONTAINING AN ESTER FUNCTION IN THE SPACER .2. SURFACE-TENSION STUDIES, Polymer international, 38(3), 1995, pp. 237-244
The surface tensions of fluorinated polysiloxanes prepared by hydrosil
ylation of unsaturated perfluoroalkyl esters derived from undecylenic
acid [CH2=CH-(CH2)(8)-COO-CH2-CH2-R(F), with R(F)=C6F13, C8F17, and C8
F17-(CH2)(10)COO-CH2-CH2-CH=CH2] by methylhydrodimethylsiloxane copoly
mers of various Si-H contents have been measured. The critical surface
tensions, gamma(c), and the solid surface tensions, gamma(S)(D), were
deduced from n-alkane and water contact angle data. They decrease as
the perfluoroalkyl graft content of the copolymers increases. Some of
them, which are in the range of the lowest surface tension fluoro poly
mers known, are observed when the fluorinated segments are self-organi
zed at the interface, i.e. when the polymers are mesomorphous or cryst
alline at room temperature.