L. Vassilev et al., SENSITIVITY OF SILVER FILMS TO H2S CONTAMINATION - ELLIPSOMETRIC AND CONDUCTIVITY STUDIES, Sensors and actuators. B, Chemical, 28(3), 1995, pp. 223-226
We have studied the growth of Ag2S film on the top of silver layers in
dilute H2S gas ambient by ellipsometric and resistivity measurements
simultaneously. The Ag2S film thickness and the normalized resistivity
change [R(t)-R(0)]R(t) follow one and the same time dependence, which
allows us to use the latter as an indicator for the H2S gas concentra
tion. The method possesses higher sensitivity at low (tens of ppm) pol
luting-gas concentrations.