METAL-COMPLEXES CONTAINING BIOLOGICALLY I MPORTANT LIGANDS .81. SYNTHESIS AND CRYSTAL-STRUCTURE OF RHODIUM(I) CHELATES WITH ALPHA-AMINO CARBOXYLATES

Authors
SEVERIN K MIHAN S BECK W
Citation
K. Severin et al., METAL-COMPLEXES CONTAINING BIOLOGICALLY I MPORTANT LIGANDS .81. SYNTHESIS AND CRYSTAL-STRUCTURE OF RHODIUM(I) CHELATES WITH ALPHA-AMINO CARBOXYLATES, Chemische Berichte, 128(11), 1995, pp. 1127-1130
Citations number
38
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
128
Issue
11
Year of publication
1995
Pages
1127 - 1130
Database
ISI
SICI code
0009-2940(1995)128:11<1127:MCBIML>2.0.ZU;2-V
Abstract
The alpha-amino carboxylate complexes (Ph(3)P)(OC)RhNH2-C(H)(R)CO2 (R = Me, CH(2)Ph = 1, 2) were prepared from Rh(Cl)(CO)(PPh(3))(2) and H2N C(H)(R)CO2- in the presence of AgBF4 and characterized by X-ray diffra ction. In the crystal the complexes form chains by hydrogen bridges be tween amino and carboxylate groups of adjacent molecules.