W. Muller et al., PRIMARY STABILIZATION FACTOR OF THE CORROSION OF HISTORICAL GLASSES -THE GEL LAYER, Glass science and technology, 68(9), 1995, pp. 285-292
Leached gel layers of variable thickness and composition, mostly criss
crossed by cracks and fissures, are built during long-term exposure of
historical glasses. Depending on the glass composition as well as on
the environmental conditions the gel layers show various shapes. They
can be characterized by microprobe investigations, through photographs
of the cross-sections in vertical plane to the corroded surface as we
ll as determination of the chemical composition. Any cleaning measures
in the course of restoration have to obey carefully their preservatio
n, for it seems quite reasonable to assume that the progress of corros
ion of the poorly resistant glasses is remarkably retarded by silica g
el barriers.