SYNTHESIS AND MOLECULAR-STRUCTURE OF THE FIRST ORGANOMETALLIC NITRIDECUBANE - [(TI(ETA(5)-C(5)ME(5)))(4)(MU(3)-N)(4)]

Authors
GOMEZSAL P MARTIN A MENA M YELAMOS C
Citation
P. Gomezsal et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF THE FIRST ORGANOMETALLIC NITRIDECUBANE - [(TI(ETA(5)-C(5)ME(5)))(4)(MU(3)-N)(4)], Journal of the Chemical Society, Chemical Communications, (21), 1995, pp. 2185-2186
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
21
Year of publication
1995
Pages
2185 - 2186
Database
ISI
SICI code
0022-4936(1995):21<2185:SAMOTF>2.0.ZU;2-X
Abstract
The ammonolysis of [Ti(eta(5)-C(5)Me(5))(NMe(2))(3)] at 90 degrees C a ffords the nitride complex [{Ti(eta(5)-C(5)Me(5))}(4)(mu(3)-N)(4)]; th e X-ray crystal structure analysis shows a Ti4N4 core clearly similar to the structural motif of cubic titanium nitride.