COORDINATION-COMPLEXES WITH INFINITE LATTICE STRUCTURES - SOLVOTHERMAL SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF K(2)M[NC5H3(CO2)(2)-2,3](2) (M=MN, ZN)
Soh. Gutschke et al., COORDINATION-COMPLEXES WITH INFINITE LATTICE STRUCTURES - SOLVOTHERMAL SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF K(2)M[NC5H3(CO2)(2)-2,3](2) (M=MN, ZN), Journal of the Chemical Society, Chemical Communications, (21), 1995, pp. 2197-2198
Reaction of MCl(2) (M = Mn, Zn) with 2 equivalents of K-2[NC5H3(CO2)(2
)-2,3] in methanol at 200 degrees C produces the compounds K(2)M[NC5H3
(CO2)(2)-2,3](2) which are found by X-ray crystallography to have stru
ctures based on interpenetrating diamondoid networks.