A. Rauscher et al., INVESTIGATION OF PHOSPHONIC ACID AND PROPARGYL ALCOHOL INHIBITORS IN HYDROCHLORIC-ACID MEDIA, ACH, models in chemistry, 132(4), 1995, pp. 589-595
The inhibitory effects of propargyl alcohol and diethylene- triamine-p
entakis (methylenephosphonic) acid were studied on carbon steel in aer
ated 5% HCl solution at 60 degrees C by the Planned Interval Test tech
nique. According to the results, the effectiveness of the propargyl al
cohol is higher than that of the phosphonic acid. The effect of the mi
xtures of the two inhibitors is not superior to the effect of the prop
argyl alcohol. The minor increase in inhibitor efficiency in shorter t
est duration caused by the phosphonic acid shows that it promotes the
adsorption of the protective species. However, during longer exposure
times it causes pitting corrosion.