INFLUENCE OF THE LIQUID-PHASE VAPOR-PRESSURE ON THE HYDROGEN SPILLOVER

Authors
KILDIBEKOVA GA ZAVYALOVA SA MIKHAILENKO SD
Citation
Ga. Kildibekova et al., INFLUENCE OF THE LIQUID-PHASE VAPOR-PRESSURE ON THE HYDROGEN SPILLOVER, Reaction kinetics and catalysis letters, 56(1), 1995, pp. 197-203
Citations number
18
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
56
Issue
1
Year of publication
1995
Pages
197 - 203
Database
ISI
SICI code
0133-1736(1995)56:1<197:IOTLVO>2.0.ZU;2-1
Abstract
Hydrogen spillover in the presence of water and alcohol vapor has been studied by semiconductor sensors. The conductivity of sensors increas es at low vapor pressure and decreases as the pressure increases. Appa rently it becomes easier for activated hydrogen to migrate from Pt to ZnO when a solvated protons form in liquid islands in the vicinity of metal particles.