ACTIVITY OF CATALYSTS IN 1-BUTANOL REACTION WITH H2S

Authors
MASHKINA AV YAKOVLEVA VN KHAIRULINA LN
Citation
Av. Mashkina et al., ACTIVITY OF CATALYSTS IN 1-BUTANOL REACTION WITH H2S, Reaction kinetics and catalysis letters, 56(1), 1995, pp. 205-211
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
56
Issue
1
Year of publication
1995
Pages
205 - 211
Database
ISI
SICI code
0133-1736(1995)56:1<205:AOCI1R>2.0.ZU;2-A
Abstract
Reaction of 1-butanol with H2S has been studied at 300 degrees C and 0 .1 MPa on catalysts of various composition. The catalysts that contain mainly strong proton sites on their surface accelerate dehydration of alcohol alone. In the presence of catalysts possessing acidic and bas ic Lewis sites 1-butanethiol is formed. Reaction rate increases as the concentration and strength of Lewis acid sites increase.