The ferromagnetic properties of ultrathin films grown on non-magnetic
substrates provide interesting new insights into the physics of magnet
ism. In this report we review experiments in the very low coverage reg
ime (- < 2 atomic layers). The Fe monolayer on W plays an outstanding
role, because it forms a ferromagnetic and thermodynamically stable mo
nolayer. Ferromagnetic Fe monolayers on W can be prepared with a high
degree of perfection. We therefore focus on ultrathin Fe films on W(11
0) and W(100) substrates. Experimental results for these in-plane magn
etized films, prepared as close as possible to a-dimensional structure
s of perfect translational symmetry, are compared with appropriate the
oretical models. We also discuss experimental results for the perpendi
cularly magnetized Co monolayer on Cu(111). The symmetry of the magnet
ic anisotropy is found to play an important role for the understanding
of the magnetic phase transition in 2 dimensions. A new aspect is pro
vided by finite size effects resulting from the morphology of magnetic
ultrathin films. Microscopy with atomic resolution allows a systemati
c approach to the understanding of these finite size effects. Starting
from the well-known magnetic properties of the extended Fe monolayer
on W(110), we focus on ultrathin Fe films on W(110) deviating from the
nearly perfect structure.