SIZE-DEPENDENT ADSORPTION MODELS IN MICROPOROUS MATERIALS .2. COMPARISON WITH EXPERIMENTAL-DATA

In this article, we complete the study of size-scaling effects and of the Keller model, presenting a detailed analysis of the application of this model to a broad range of experimental data on microporous mater ials (in particular, activated carbon and zeolites). Particular attent ion is focused on the temperature dependence of the Freundlich exponen ts ai, on the functional form of the adsorption energies, and on the a pplication of Keller adsorption isotherms in a predictive way to gener ic multicomponent mixtures.