CONJUGATE ADDITION-REACTIONS OF ALPHA-AZOALKYLCUPRATE REAGENTS

Citation
Cw. Alexander et al., CONJUGATE ADDITION-REACTIONS OF ALPHA-AZOALKYLCUPRATE REAGENTS, Journal of organometallic chemistry, 503(2), 1995, pp. 213-220
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
503
Issue
2
Year of publication
1995
Pages
213 - 220
Database
ISI
SICI code
0022-328X(1995)503:2<213:CAOAR>2.0.ZU;2-9
Abstract
A new class of alpha-heteroatomalkyl organocuprate/organocopper reagen ts has been prepared. These alpha-azoalkyl cuprate reagents were deriv ed from alpha-azoalkyl anions and were treated with enones and enoates affording gamma-azoalkyl carbonyl compounds in modest yields.