ORGANOTIN(IV) POLYPYRAZOLYBORATES .8. HYDRIDOTRIS (4-CHLORO-3,5-DIMETHYL-1H-PYRAZOL-1-YL)BORATES - CHARACTERIZATION, MOSSBAUER STUDY AND X-RAY CRYSTAL-STRUCTURES OF [SNCL3(HB(4-CL-3,5-ME(2)PZ)(3)] AND [PHSNCL(2)(HB(4-CL-3,5-ME(2)PZ))(3)]

Authors
LOBBIA GG CECCHI P CALOGERO S VALLE G CHIARINI M STIEVANO L
Citation
Gg. Lobbia et al., ORGANOTIN(IV) POLYPYRAZOLYBORATES .8. HYDRIDOTRIS (4-CHLORO-3,5-DIMETHYL-1H-PYRAZOL-1-YL)BORATES - CHARACTERIZATION, MOSSBAUER STUDY AND X-RAY CRYSTAL-STRUCTURES OF [SNCL3(HB(4-CL-3,5-ME(2)PZ)(3)] AND [PHSNCL(2)(HB(4-CL-3,5-ME(2)PZ))(3)], Journal of organometallic chemistry, 503(2), 1995, pp. 297-305
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
503
Issue
2
Year of publication
1995
Pages
297 - 305
Database
ISI
SICI code
0022-328X(1995)503:2<297:OP.H(>2.0.ZU;2-G
Abstract
Five tin(IV) and organotin(IV) hydridotris(4-chloro-3,5-dimethyl-1 H-p yrazol-1-yl)borates have been synthesized and characterized by H-1, C- 13 and Sn-119 NMR and Sn-119m Mossbauer spectroscopy. The tin atom has a more or less distorted octahedral coordination both in the solid st ate and in solution. The X-ray crystal structures of trichlorotin(IV) and dichlorophenyltin(IV) hydridotris [4-chloro-3,5-dimethyl-1H- -pyra zol-1-yl)borates confirm these inferences.