N. Lequeux et al., SHRINKAGE REDUCTION IN SILICA-BASED REFRACTORY CORES INFILTRATED WITHBOEHMITE, Journal of the American Ceramic Society, 78(11), 1995, pp. 2961-2966
Infiltration of silica-based refractory cores with colloidal boehmite
slurry has the effect of greatly reducing sintering shrinkage, as requ
ired for precision casting. Only 300 ppm of equivalent alumina is suff
icient to decrease the shrinkage from RT to 1600 degrees C more than t
hree-fold. Microstructural observations and XPS measures show that the
silica grains are homogeneously coated with a reaction film which hin
ders viscous flow.