METALLO-SILANOLS AND METALLO-SILOXANES .12. SYNTHESIS AND REACTIVITY OF SILICON TRANSITION-METAL COMPLEXES .38. C(5)R(5)(OC)(2)(ME(3)P)M-SUBSTITUTED SILANETRIOLS OF MOLYBDENUM AND TUNGSTEN (R=H, ME) - SYNTHESIS VIA OXOFUNCTIONALIZATION OF METALLOTRIHYDRIDOSILANES AND TRANSFORMATION INTO THE MULTIFUNCTIONALIZED METALLOTETRASILOXANE C(5)ME(5)(OC)(2)(ME(3)P)WSI(OSIME(2)H)(3)

Authors
MALISCH W LANKAT R SCHMITZER S REISING J
Citation
W. Malisch et al., METALLO-SILANOLS AND METALLO-SILOXANES .12. SYNTHESIS AND REACTIVITY OF SILICON TRANSITION-METAL COMPLEXES .38. C(5)R(5)(OC)(2)(ME(3)P)M-SUBSTITUTED SILANETRIOLS OF MOLYBDENUM AND TUNGSTEN (R=H, ME) - SYNTHESIS VIA OXOFUNCTIONALIZATION OF METALLOTRIHYDRIDOSILANES AND TRANSFORMATION INTO THE MULTIFUNCTIONALIZED METALLOTETRASILOXANE C(5)ME(5)(OC)(2)(ME(3)P)WSI(OSIME(2)H)(3), Inorganic chemistry, 34(23), 1995, pp. 5701
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
23
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:23<5701:MAM.SA>2.0.ZU;2-J
Abstract
The metallotrihydrosilanes C(5)R(5)(OC)(2)(Me(3)P)MSiH(3) (R = H, Me, M = Mo, W (1a-c)) are converted with dimethyldioxirane to the metallos ilanetriols 2a-c. Condensation of 2c with Me(2)Si(H)Cl (3) gives acces s to the branched Si-H-functionalized metallotetrasiloxane 4.