SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW RARE-EARTH SELENODIPHOSPHATE(IV) - KLAP2SE6

Authors
CHEN JH DORHOUT PK
Citation
Jh. Chen et Pk. Dorhout, SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW RARE-EARTH SELENODIPHOSPHATE(IV) - KLAP2SE6, Inorganic chemistry, 34(23), 1995, pp. 5705
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
23
Year of publication
1995
Database
ISI
SICI code
0020-1669(1995)34:23<5705:SASCOA>2.0.ZU;2-5
Abstract
The high-temperature, molten alkali-metal polyselenide salt reaction o f the elements yielded a new, porous-layered rare-earth selenodiphosph ate(IV), KLaP2Se6, that comprises uniquely bound [P2Se6](4-) units tha t bind lanthanum atoms through face-capping interactions. This is the first known rare-earth selenodiphosphate(IV) compound.