A. Burgess et al., HIGH-ENERGY BORN COLLISION STRENGTHS FOR OPTICALLY FORBIDDEN TRANSITIONS, Journal of physics. B, Atomic molecular and optical physics, 30(1), 1997, pp. 33-57
Collision strengths for optically forbidden transitions in positive io
ns excited by electron impact tend to finite limits as the energy of t
he colliding electron becomes infinitely great. This statement applies
to theoretical data obtained by means of approximations which ignore
relativistic effects. The high-energy limiting values are given by the
Born approximation, which Bethe showed can be reduced to a closed exp
ression requiring integration over momentum transfer and the radial di
stance of the atomic orbital. In the appendix we describe an accurate
numerical procedure for evaluating this double integral and also show
how to perform the Racah algebra which arises when mixed configuration
s are used to describe the target. We make applications to several iso
electronic sequences taking configuration interaction into account.