SYNTHESIS OF A TETRAKIS(9-ANTHRYL) SUBSTITUTED PORPHYRIN AND INTRAMOLECULAR CHARGE-TRANSFER EMISSION IN ITS DICATION

Authors
NAKAJIMA S OSUKA A
Citation
S. Nakajima et A. Osuka, SYNTHESIS OF A TETRAKIS(9-ANTHRYL) SUBSTITUTED PORPHYRIN AND INTRAMOLECULAR CHARGE-TRANSFER EMISSION IN ITS DICATION, Tetrahedron letters, 36(46), 1995, pp. 8457-8460
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
46
Year of publication
1995
Pages
8457 - 8460
Database
ISI
SICI code
0040-4039(1995)36:46<8457:SOATSP>2.0.ZU;2-Y
Abstract
Tetrakis(9-anthryl) substituted porphyrin 1 was synthesized. In the pr esence of TFA, the porphyrin moiety was protonated to form dication wh ich, upon excitation, accepts an electron from the anthryl moiety to y ield an emissive CT state.