1-(BENZOYLAMINO)-3-METHYLIMIDAZOLIUM CHLOROCHROMATE (BAMICC), A NEW SELECTIVE AND MILD REAGENT FOR THE OXIDATION OF ALLYLIC AND BENZYLIC ALCOHOLS

Authors
MARTINEZ Y DELASHERAS MA VAQUERO JJ GARCIANAVIO JL ALVAREZBUILLA J
Citation
Y. Martinez et al., 1-(BENZOYLAMINO)-3-METHYLIMIDAZOLIUM CHLOROCHROMATE (BAMICC), A NEW SELECTIVE AND MILD REAGENT FOR THE OXIDATION OF ALLYLIC AND BENZYLIC ALCOHOLS, Tetrahedron letters, 36(46), 1995, pp. 8513-8516
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
46
Year of publication
1995
Pages
8513 - 8516
Database
ISI
SICI code
0040-4039(1995)36:46<8513:1C(ANS>2.0.ZU;2-S
Abstract
A new mild chromium(VI) oxidizing reagent, the 1-(benzoylamino)-3-meth ylimidazolium chlorochromate (BAMICC) has been prepared as a stable ye llow-orange solid which selectively oxidizes allylic and benzylic alco hols, including those bearing basic nitrogens, to carbonyl compounds.