ELECTROCATALYTIC OXIDATION OF SUCROSE - ANALYSIS OF THE REACTION-PRODUCTS

Authors
PARPOT P KOKOH KB BELGSIR EM LEGER JM BEDEN B LAMY C
Citation
P. Parpot et al., ELECTROCATALYTIC OXIDATION OF SUCROSE - ANALYSIS OF THE REACTION-PRODUCTS, Journal of Applied Electrochemistry, 27(1), 1997, pp. 25-33
Citations number
11
Categorie Soggetti
Electrochemistry
Journal title
Journal of Applied Electrochemistry → ACNP
ISSN journal
0021891X
Volume
27
Issue
1
Year of publication
1997
Pages
25 - 33
Database
ISI
SICI code
0021-891X(1997)27:1<25:EOOS-A>2.0.ZU;2-M
Abstract
The analysis of sucronic acids produced by the electrocatalytic oxidat ion of sucrose is described. The main reaction products, 1'-monocarbox ylic and 6-monocarboxylic acids of sucrose, were identified by means o f gas and liquid chromatography, mass spectrometry, NMR and i.r. spect roscopy, and acid hydrolysis. The quantitative analysis of reaction pr oducts other than the sucronic acids was realized by ionic chromatogra phy (Dionex), whereas that of the sucronic acids was carried out using their acid hydrolysis products.