DEHYDROHALOGENATION OF IODOARENES TO GIVE RUTHENIUM CLUSTERS CONTAINING MU(4)-NAPHTHYNE AND MU(4)-PHENANTHRYNE LIGANDS

Authors
DEEMING AJ SPEEL DM
Citation
Aj. Deeming et Dm. Speel, DEHYDROHALOGENATION OF IODOARENES TO GIVE RUTHENIUM CLUSTERS CONTAINING MU(4)-NAPHTHYNE AND MU(4)-PHENANTHRYNE LIGANDS, Organometallics, 16(3), 1997, pp. 289-291
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
3
Year of publication
1997
Pages
289 - 291
Database
ISI
SICI code
0276-7333(1997)16:3<289:DOITGR>2.0.ZU;2-D
Abstract
Iodobenzene and 4-iodotoluene react with [Ru-3(CO)(12)] to give the ox idative addition products [Ru-3(mu-I)(mu,eta(6)-C(6)H(4)R)(CO)(8)] (R = H, 4-Me), whereas 1-iodonaphthalene and 9-iodophenanthrene give the aryne clusters [Ru-4(mu(4),eta(2)-L)(CO)(12)] (L = 1,2-naphthyne, 9,10 -phenanthryne).