OXIDATIVE ADDITION OF A SI-C(SP) BOND TO RUTHENIUM - SYNTHESIS AND REACTIVITY OF RU(SIME(3))(C-CSIME(3))(CO)(P(T)BU(2)ME)(2)

Authors
HUANG DJ HEYN RH BOLLINGER JC CAULTON KG
Citation
Dj. Huang et al., OXIDATIVE ADDITION OF A SI-C(SP) BOND TO RUTHENIUM - SYNTHESIS AND REACTIVITY OF RU(SIME(3))(C-CSIME(3))(CO)(P(T)BU(2)ME)(2), Organometallics, 16(3), 1997, pp. 292-293
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
3
Year of publication
1997
Pages
292 - 293
Database
ISI
SICI code
0276-7333(1997)16:3<292:OAOASB>2.0.ZU;2-O
Abstract
Me(3)SiC=CSiMe(3) reacts with Ru(H)(2)(CO)L(2) (L = P(t)Bu(2)Me) to gi ve Ru(SiMe(3))(CCSiMe(3))(CO)L(2), characterized by solution spectrosc opic and single-crystal X-ray diffraction methods. The molecule is squ are-pyramidal with an apical SiMe(3) group and CO and CCSiMe(3) in mut ually trans basal sites.