PHOSPHORUS-CONTAINING DENDRIMERS AS MULTIDENTATE LIGANDS - PALLADIUM,PLATINUM, AND RHODIUM COMPLEXES

Authors
BARDAJI M KUSTOS M CAMINADE AM MAJORAL JP CHAUDRET B
Citation
M. Bardaji et al., PHOSPHORUS-CONTAINING DENDRIMERS AS MULTIDENTATE LIGANDS - PALLADIUM,PLATINUM, AND RHODIUM COMPLEXES, Organometallics, 16(3), 1997, pp. 403-410
Citations number
63
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
3
Year of publication
1997
Pages
403 - 410
Database
ISI
SICI code
0276-7333(1997)16:3<403:PDAML->2.0.ZU;2-M
Abstract
New dendrimers 3-[G'(1)]-3-[G'(4)] possessing from 6 to 48 N(CH(2)PPh( 2))(2) terminal groups are described. The corresponding Pd, Pt, and Ph complexes [N(CH(2)PPh(2))(2)MRR'](y) (y from 6 to 24; generations 1-3 ) [M = Pd: R = R' = Cl, Br; R = Cl, R' = Me; R = Br, R' = Me; R = Cl, R' = COMe; R = Cl, R' = norbornyl-COMe. M = Pt: R = R' = Br, Cl, Me; R = Br, R' = Me. M = Ph: R, R' = acac] are prepared by reacting 3-[G'(1 )]-3-[G'(3)] with the appropriate transition metal complexes.