DIIRON COMPLEX WITH 3 BRIDGING SILYL SUBSTITUENTS

Authors
SIMONS RS TESSIER CA
Citation
Rs. Simons et Ca. Tessier, DIIRON COMPLEX WITH 3 BRIDGING SILYL SUBSTITUENTS, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1997-1998
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
10
Pages
1997 - 1998
Database
ISI
SICI code
0108-2701(1995)51:<1997:DCW3BS>2.0.ZU;2-J
Abstract
The crystal structure of methylsilyl)-bis[mu-(dimethylsilyl)]diiron(Fe -Fe), [Fe-2(CH3Cl-Si)(C2H6Si)(2)(CO)(6)], has been determined. The Fe- Fe distance is 2.705(1) Angstrom and the Fe-Si distances are 2.322(3) Angstrom. The combination of the sixfold screw axis and the uniqueness of the bridging SiMeCl moiety create rotational disorder within the u nit cell.