O-O-O')BIS(N,N-DIETHYLNICOTINAMIDE-N')DICOPPER(II)

Citation
T. Hokelek et al., O-O-O')BIS(N,N-DIETHYLNICOTINAMIDE-N')DICOPPER(II), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2020-2023
Citations number
14
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
10
Pages
2020 - 2023
Database
ISI
SICI code
0108-2701(1995)51:<2020:O>2.0.ZU;2-B
Abstract
The title molecule, [CU2(Cu6H5COO)(4)(C10H14N2O)(2)], is a crystallogr aphically centrosymmetric binuclear complex, with Cu atoms [Cu...Cu' = 2.613 (1) Angstrom] bridged by four benzoate ligands. The four neares t O atoms around each Cu atom form a square-planar arrangement with th e square-pyramidal coordination completed by the pyridine N atom of th e N,N(-diethylnicotinamide ligand at a distance of 2.162(6) Angstrom. Each Cu atom is displaced by 0.190 (1) Angstrom from the plane of the four O atoms, with an average Cu-O distance of 1.974(6) Angstrom.