AN ANALYSIS OF THE DEUTERIUM EQUILIBRIUM ISOTOPE EFFECT FOR THE BINDING OF ETHYLENE TO A TRANSITION-METAL COMPLEX

Authors
Citation
Br. Bender, AN ANALYSIS OF THE DEUTERIUM EQUILIBRIUM ISOTOPE EFFECT FOR THE BINDING OF ETHYLENE TO A TRANSITION-METAL COMPLEX, Journal of the American Chemical Society, 117(45), 1995, pp. 11239-11246
Citations number
59
Categorie Soggetti
Chemistry
ISSN journal
00027863
Volume
117
Issue
45
Year of publication
1995
Pages
11239 - 11246
Database
ISI
SICI code
0002-7863(1995)117:45<11239:AAOTDE>2.0.ZU;2-G
Abstract
The secondary deuterium equilibrium isotope effect (EIE) for the rever sible binding of C2H4 to (mu-eta(1),eta(1)-C2H4)O-s2(CO)(8) (1) and C2 D4 to (mu-eta(1)-eta(1),-C2D4)O-s2(CO)(8)(1-d(4)) has been measured in dodecane solvent. The measured EIE is ''inverse'' (C2D4 binds better than C2H4) and has a value of K-H/K-D = 0.7(L) at 313 K (40 degrees C) where K-H/K-D [C2D4](s)[1]/[C2H4]((s))[1-d(4)]. Previously published vibrational assignments for 1 and 1-d(4) and literature values for C2H 4 and C2D4 allowed the calculation of the same EIE using 16 isotopical ly sensitive vibrational modes for both 1 and 1-d(4) and all 12 vibrat ional modes for both C2H4 and C2D4. The calculated EIE is also ''inver se'' and has a value of 0.7110 at 313 K (40 degrees C). The EIE calcul ated from vibrational frequencies may be resolved into a mass and mome nt of inertia factor (MMI = 2.272), a vibrational excitation factor (E XC = 0.8820), and a zero-point energy factor (ZPE = 0.3548), where EIE = MMI x EXC x ZPE. Using symmetry correlation rules, contributions to the EXC and ZPE factors from changes in ethylene vibrational modes fo r individual modes may be determined. The MMI component may be further resolved into translation and rotational contributions with the help of moments of inertia calculated from a previously determined single-c rystal neutron diffraction structure of 1. The analysis reveals that, contrary to expectation, most of the EIE is not due to changes in vibr ational frequencies common to free and complexed ethylene upon coordin ation but is instead primarily due to a zero-point energy factor from a vibrational mode (a b(2)-symmetry twist) for 1 and 1-d(4) which is n ot present in free ethylene. This interpretation of the observed ''inv erse'' EIE appears to be general for alkene complexation and may under lie other recently observed ''inverse'' secondary deuterium equilibriu m isotope effects for the coordination of small molecules (including a lkanes and dihydrogen) to transition-metal complexes.