A measurement theory for the temperature of relativistic systems is de
veloped. The resulting operational approach is shown to be quasi-local
and therefore may be applicable in general Riemannian manifolds even
when there are temperature gradients which induce heat flows. The surp
rising feature of our analysis is that it leads to a bifurcation of th
e temperature concept into two distinctly different measurable quantit
ies: one a frame invariant scalar field which a local co-moving observ
er would tend to identify with the local temperature and employ in the
definition of entropy, the other a frame dependent, but nevertheless
locally determinable quantity which governs the flow of heat and the a
bility to extract work. The two quantities differ by the bookkeeping m
ethodology employed to calibrate the thermometer. A simple relationshi
p between the two temperatures can be established if a preferred Killi
ng vector held is available in the Riemannian manifold.