K3FE3(PO4)(4)CENTER-DOT-H2O - AN IRON(III) PHOSPHATE WITH A LAYER STRUCTURE

Authors
LII KH
Citation
Kh. Lii, K3FE3(PO4)(4)CENTER-DOT-H2O - AN IRON(III) PHOSPHATE WITH A LAYER STRUCTURE, European journal of solid state and inorganic chemistry, 32(9), 1995, pp. 917-926
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
32
Issue
9
Year of publication
1995
Pages
917 - 926
Database
ISI
SICI code
0992-4361(1995)32:9<917:K-AIPW>2.0.ZU;2-T
Abstract
An Fe-III phosphate, K3Fe3(PO4)(4) . H2O, has been synthesized by high -temperature/high-pressure hydrothermal method and characterized by si ngle-crystal X-ray diffraction. The compound crystallizes in the ortho rhombic space group Pnna with a = 10.717(1), b = 20.823(4), c = 6.5296 (9) Angstrom, V = 1457.1(4) Angstrom(3) and Z = 4. The structure is ba sed on a sheet involving corner-linkage between FeO6 octahedra, and co rner- and edge-sharing between FeO6 octahedra and PO4 tetrahedra. The sheets are linked by 7- or 6-oxygen coordinated K+ cations and hydroge n bonding.