SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW BINUCLEAR ORGANOIRON NONBRIDGED COMPLEX - BIS(TERT-BUTOXYCARBONYL)OCTACARBONYLDIIRON, [FE(CO(2)(T)BU)(CO)(4)](2)

Authors
LUART D SELLIN M LAURENT P SALAUN JY PICHON R TOUPET L ABBAYES HD
Citation
D. Luart et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW BINUCLEAR ORGANOIRON NONBRIDGED COMPLEX - BIS(TERT-BUTOXYCARBONYL)OCTACARBONYLDIIRON, [FE(CO(2)(T)BU)(CO)(4)](2), Organometallics, 14(11), 1995, pp. 4989-4991
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
11
Year of publication
1995
Pages
4989 - 4991
Database
ISI
SICI code
0276-7333(1995)14:11<4989:SACOAN>2.0.ZU;2-S
Abstract
The reaction of Na[Fe(CO(2)(t)Bu)(CO)(4)] with 0.5 equiv of ClCOCOCl i n tetrahydrofuran affords the new complex [Fe(CO(2)(t)Bu)(CO)(4)](2), which is characterized by single-crystal X-ray diffraction analysis. S tructural and spectroscopic observations show that it does not present any bridging ligands.