UNSTABLE SPECIES, CPW(CO)(2)ME AND CPW(CO)(3), STUDIED BY TIME-RESOLVED INFRARED-SPECTROSCOPY

Authors
VIRRELS IG GEORGE MW JOHNSON FPA TURNER JJ WESTWELL JR
Citation
Ig. Virrels et al., UNSTABLE SPECIES, CPW(CO)(2)ME AND CPW(CO)(3), STUDIED BY TIME-RESOLVED INFRARED-SPECTROSCOPY, Organometallics, 14(11), 1995, pp. 5203-5208
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
11
Year of publication
1995
Pages
5203 - 5208
Database
ISI
SICI code
0276-7333(1995)14:11<5203:USCACS>2.0.ZU;2-V
Abstract
Photolysis of CpW(CO)(3)Me (1) in n-heptane generates mostly the solva ted intermediate CpW(CO)(2)Me ... n-heptane (2), detected by time-reso lved infrared spectroscopy (TRIR). The reactions of 2 with CO, PPh(3), and N-2 have been studied and appropriate second-order rate constants obtained. A small amount of the radical CpW(CO)(3.) (5) is also gener ated on photolysis of 1 and can be characterized by the photolysis of [CpW(CO)(3)](2) (6).