Yb. Bolkhovityanov, ELASTICALLY STRAINED INGAASP FILMS GROWN BY LPE AND CONCEPTION OF STRESS-INDUCED SUPERCOOLING, Physica status solidi. a, Applied research, 151(2), 1995, pp. 363-370
The pseudomorphic InGaAsP films with elastic strains up to 1% are grow
n on GaAs substrates of (111)B orientation by liquid phase epitaxy (LP
E). The evolution of morphology with an increase of elastic strain in
the films is analysed. A new mechanism of elastic strain relaxation du
ring InGaAsP film growth is discovered. It consists in the appearance
of unstrained islands in the InGaAsP strained film and their lateral s
preading till they come together. The fundamental limit of elastic str
ains to about 1% in the InGaAsP films grown by LPE is connected with t
he stress-induced supercooling that appears and increases with the str
esses in the film and, at last, compensates the initial supercooling o
f the liquid. The time required for the growth of the elastically stra
ined films does not exceed a few seconds. At longer duration of the gr
owth unstrained parts of the film spread laterally and cover the whole
surface of the substrate with a highly mismatched unstrained layer of
poor crystal quality.